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Synthesis of tert -Butyl (R)-(3-(3-chlorophenyl)-1-oxo-1-(4-(1-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]quinolin-7-yl)piperazin-1-yl)propan-2-yl)carbamate (8r) Intermediate 6d was treated with commercial compound 7e according to general procedure 8a-8u